Dynamic kinetic resolution in chemistry is a type of kinetic resolution where 100% of a racemic compound can be converted into an enantiopure compound. It is applied in asymmetric …

This process is known as dynamic kinetic resolution (DKR). DKR is an example of a Curtin-Hammett system in which the composition of products is controlled by the free energies of the …

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In a DKR, the rate of racemization of SM is fast relative the rate of the asymmetric transformation. Thus, using DKR, possible to convert 100% of racemic SM to enantiopure product due to …

Feb 9, 2022 · Dynamic kinetic resolution (DKR) is a powerful method to construct complex molecules with one or more stereocenters. In light of their exquisite stereospecificity and …

May 27, 2011 · In DKR, the enantiomers of a racemic substrate are induced to equilibrate at a rate that is faster than that of the slow-reacting enantiomer in reaction with the chiral reagent …

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Dec 23, 2022 · In this work, we report the highly regio- and stereoselective asymmetric semi-transfer hydrogenation of unsymmetrical α-diketones through a unique DKR mode, which …

Apr 1, 2007 · In situ racemization of the slow-reacting enantiomer leads to an overall deracemization by dynamic kinetic resolution (DKR), and makes it possible to achieve a 100% …

May 2, 2014 · This overall process would allow the conversion of a racemic mixture into a single enantiomer through an in situ stereoinversion, which is defined as dynamic kinetic resolution …